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c1ccccc1

c1ccccc1
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maROCARBONS Acetophenone (ii) (13.77) In the case of nitration, the electrophile. nitronium ion. is produced by transfer of a proton (from sulphuric acid) to nitric acid in the following manner: (13.78) Step I If excess of electrophilic reagent is used. further substitution reaction may take place In which other hydrogen atoms of benzene ring may also be successively replaced by the electrophile. For example benzene on atment with excess of chlorine in the sence of anhydrous can be Srinated to hexachlorobenzene It is interesting to note that in the process of generation of nitronlum ion, sulphuric acid serves as an acid and nltric acid as a base. Thus, it is a simple acid-base equilibrium. (b) Formation of Carbocation (arenium ion): Attack of electrophile Mechanism of electrophflic substitution (13.79) - arentum ion in which one of the carbon is or reactions: According to experimental evidences, (S = substitution; electrophilic) reactions are supposed to proceed via the following three steps: (a) Generation of the eletrophile (b) Formation of carbocation intermediate The arenium ion gets stabilised by hybridised. (c) Removal of proton from the carbocation - resonance: intermediate (a) Generation of electrophile : During chlorination, alkylation and acylation of benzene, anhydrous , being a Lewis acid helps in generation of the elctrophile . (acylium ion) respectively by combining with the attacking reagent.
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Question Text
c1ccccc1
Updated OnMar 30, 2024
TopicHydrocarbons
SubjectChemistry
ClassClass 12
Answer Type Video solution: 1
Upvotes58
Avg. Video Duration1 min