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Question 24
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OR 293 pefine and . Prove that , where symbols have their usual gings. OR (H.P.B. 2008) ghow that for an ideal gas : . (H.P.U. 2015) OR (H.P.B. 2021) lar Specific Heat at Constant Volume : It is defined as the amount of constant volume. It is denoted by . (1) Molar Specific Heat at Constant Pressure : It is defined as the amount of heat auired to raise the temperature of 1 mole of a gas through 1 degree Celsius, at (nstant pressure. It is denoted by Consider one mole of a gas in a vessel fitted with an airtight piston. Let be (e) area of cross section of the piston. Let the gas be heated at constant volume. The (2) persure on the gas has to be increased to keep its volume constant. Let be the pat supplied at constant volume such that the temperature of the gas increases by IT. If is the molar specific heat of the gas at constant volume, then (3) Now let the gas be heated at constant pressure. This is done by removing the done axcess pressure on the piston. This increases the volume of the gas to . Let Q2 be the heat supplied at constant pressure. If is the molar specific heat at ..(4) constant pressure and the gas be heated through a temperature , then At constant pressure the heat supplied not only raises the temperature through IT but also does mechanical work. If is the mechanical work done by the gas in pushing the piston outwards, then If the piston is pushed outwards through a distance , then the small work done s given by Substituting equations (1), (2) and (4) in equation (3), we have For one mole of a gas the perfect gas equation is , differentiating both sides of this equation, at constant pressure, we have Substituting in equation (6), we have or
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