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(d) Elimination is favoured.
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Center is the stability of the stated ammonium calon stringer should be the corresponding imine on a hone. Thus, the order of try if aliphatte amies should be primary aindary tertiary which in opposite in the todoctive effect based order Secondly, when the CH there is no sterte indraser to alkyl group is small ke be sterte hirderance to H feiding. Therefore, the change of nature of 11-bonding In case the alkyl grop is hier than CH, group, there will the alloyl group eat from it, in CH, reeds in change of the onder of basic strength Thus, there is a subtle interplay of the indiv effect, solvation effect and steric funderance of the alleyl group which decides the basic strength of alkyl amines in the aqueos state The order of baste strength in case of methyl substituted amnes and ey substituted amines in aqueous solution is as followe (C HỘNH: KIMONG CỤMÌNH, NH, KHÍNH CHÍNH, KHÔNG SINH, (b) Arylamines versus ammonia pk, value of aniline is quite high. Why is it so it is because in aniline or other arylamines, the NH, group is attached directly to the benzene ring. It results in the unshared electron pair on nitroen atom to be in conjugation with the benzene ring and thus making it less available for protonation. If you write different resonating structures of aniline, you will find that andline is a resonance hybrid of the following five structures. NH, S 1 NH ← NH. III NH. IV 1 On the other hand, anilinium ion obtained by accepting a proton can have only two resonating structures (kekule). NH, NH, 1) NH, (2) V 1 11 We know that greater the number of resonating structures, greater is the stability. Thus you can infer that aniline (five resonating structures) is more stable than anilinium ion. Hence, the proton acceptability or the basic nature of aniline or other aromatic amines would be less than that of ammonia. In case of substituted aniline, it is observed that electron releasing groups like -OCH,. -CH, Increase basic strength whereas electron withdrawing groups like -NO,. -SOH. -COOH. -X decrease it. 399, Amitnes coordination niodes Amines 10) Hoff
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Question Text
TopicAlcohols, Phenols and Ethers
SubjectChemistry
ClassClass 12
Answer TypeText solution:1
Upvotes125