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2NO+2H2​→N2​+2H2​O
The above reaction has been studied at 800∘C. The r

The above reaction has been studied at . The related data are given in the table below
Reaction$\begin{array}{c}\text { Initial Pressure of }
\text { serial number }\end{array}\begin{array}{c}\text { Initial Pressure }
\text { of } \mathrm{NO} / \mathrm{kPa}\end{array}\begin{array}{c}\text { Initial rate }
\left(\frac{-d p}{d t}\right) /(\mathrm{kPa} / \mathrm{s})\end{array}$
165.640.00.135
265.620.10.033
338.665.60.214
419.265.60.106
The order of the reaction with respect to NO is

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III Integrated We have already noted that the concentration dependence of rate is Rate called differential rate equation. It is not always convenient to Equations of slope of the tantaneous rate, as it is measured by determination (Fig. 4.1). This makes it difficult to in concentration vs ime plot the order of the reaction. In order tormine the rate law and hence integrate the differential rate equation to give a relation between directly measured experimental data, i.e., concentrations at different times and rate constant. The integrated rate equations are different for the reactions of different reaction orders. We shall determine these equations only for zero and first order chemical reactions, 1 Zero Order Zero order reaction means that the rate of the reaction is proportional Reactions to zero power of the concentration of reactants. Consider the reaction, \[ \begin{array}{l} \mathrm{R} \rightarrow \mathrm{P} \\ \text { Rate }=-\frac{\mathrm{d}[\mathrm{R}]}{\mathrm{d} t}=k[\mathrm{R}]^{0} \end{array} \] As any quantity raised to power zero is unity \[ \begin{array}{l} \text { Rate }=-\frac{\mathrm{d}[\mathrm{R}]}{\mathrm{d} t}=k \times 1 \\ \mathrm{~d}[\mathrm{R}]=-k \mathrm{~d} t \end{array} \] Integrating both sides where. is the constant of integration. At , the concentration of the reactant , where is initial concentration of the reactant. Substituting in equation (4.5) \[ \begin{array}{l} {[\mathrm{R}]_{0}=-k \times 0+1} \\ {[\mathrm{R}]_{0}=\mathrm{I}} \end{array} \] Substituting the value of in the equation (4.5) \[ [\mathrm{R}]=-k t+[\mathrm{R}]_{0} \] 165. Chemical Kinetics
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Question Text
The above reaction has been studied at . The related data are given in the table below The order of the reaction with respect to NO is
Updated OnMar 18, 2023
TopicChemical Kinetics
SubjectChemistry
ClassClass 12
Answer Type Video solution: 1
Upvotes56
Avg. Video Duration6 min