Question
Which of the following complexes exhibits the highest paramagnetic behaviour?
where gly=glycine, en=ethylenediamine and bipy =bipyridyl
(At. no. )



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The electronic configuration of
Let in oxidation state of V is x.
(no unpaired electrons)
Theelectronic configuration of
Let the oxidation state of is x.
but, bpy, en and all are strong field ligands, so pairing occurs and thus, contains no unpaired electron
The electronic configuration of
Let the oxidation state Co in is x
[4 unpaired electrons]
ox and OH are weak field ligands, thus pairing of electron units does not occur.
The electronic configuration of
Oxidation state of Ti in is 3.
(one unpaired electron) Hence, complex has maximum number of unpaired electrons, thus show maximum paramagnetism
Let in oxidation state of V is x.
(no unpaired electrons)
Theelectronic configuration of
Let the oxidation state of is x.
but, bpy, en and all are strong field ligands, so pairing occurs and thus, contains no unpaired electron
The electronic configuration of
Let the oxidation state Co in is x
[4 unpaired electrons]
ox and OH are weak field ligands, thus pairing of electron units does not occur.
The electronic configuration of
Oxidation state of Ti in is 3.
(one unpaired electron) Hence, complex has maximum number of unpaired electrons, thus show maximum paramagnetism
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Question Text | Which of the following complexes exhibits the highest paramagnetic behaviour? where gly=glycine, en=ethylenediamine and bipy =bipyridyl (At. no. ) |
Answer Type | Text solution:1 |
Upvotes | 152 |