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The increasing order of basicity of the following compounds is 
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Among the given compounds the basic nature depends upon their tendency to donate electron pair.
Among the given compounds in 
Nitrogen is -hybridised.
This marginally increases the electronegativity of nitrogen which in turn decreases the electron donation tendency of nitrogen.
Thus making compound least basic.
Among the rest is totally different from others as in this compound lone pair of one nitrogen are in conjugation with bond i.e.
As a result of this conjugation the cation formed after protonation becomes resonance stabilised
This equivalent resonance in cation makes
Categorisation is very simple between rest two as
Hence, the correct order is
(II) (I) (IV) (III)
i.e. option (c) is correct.
Nitrogen is -hybridised.
This marginally increases the electronegativity of nitrogen which in turn decreases the electron donation tendency of nitrogen.
Thus making compound least basic.
Among the rest is totally different from others as in this compound lone pair of one nitrogen are in conjugation with bond i.e.
As a result of this conjugation the cation formed after protonation becomes resonance stabilised
This equivalent resonance in cation makes
Categorisation is very simple between rest two as
Hence, the correct order is
(II) (I) (IV) (III)
i.e. option (c) is correct.Was this solution helpful?
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| Question Text | The increasing order of basicity of the following compounds is |
| Updated On | Sep 14, 2023 |
| Topic | Amines |
| Subject | Chemistry |
| Class | Class 12 |
| Answer Type | Text solution:1 Video solution: 9 |
| Upvotes | 1053 |
| Avg. Video Duration | 4 min |
