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Chemistry Part-I

Coordination Compounds

Discuss the nature of bonding in the following coordination en

Chemistry Part-I

Class 12

NCERT

Chapter 1: The Solid State

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Chapter 2: Solutions

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Chapter 3: Electrochemistry

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Chapter 4: Chemical Kinetics

40 questions

Chapter 5: Surface Chemistry

27 questions

Chapter 6: General Principles and Processes of Isolation of Elements

30 questions

Chapter 7: The p-Block Elements

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Chapter 8: The d-and f-Block Elements

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Chapter 9: Coordination Compounds

38 questions

What is the coordination entity formed when excess of aqueous

K CN

is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when

H_{2} S (g)

is passed through this solution?

Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i)

[F e (CN)_{6}]^{4 -}

(ii)

[F e F_{6}]^{3 -}

(iii)

[C o (C_{2} O_{4})_{3}]^{3 -}

(iv)

[C o F_{6}]^{3 -}

Draw figure to show the splitting of d orbitals in an octahedral crystal field.

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Question

Hard

Solving time: 10 mins

Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i) $[F e (CN)_{6}]^{4 -}$ (ii) $[F e F_{6}]^{3 -}$ (iii) $[C o (C_{2} O_{4})_{3}]^{3 -}$ (iv) $[C o F_{6}]^{3 -}$

Name: Video solution 1: [Solved] Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:(i) [Fe(CN)6]4− (ii) [FeF6]3− (iii) [Co(C2O4)3]3− (iv) [CoF6]3− - Chemistry Part-I
Uploaded: 2022-11-02T04:17:43.000Z
Duration: 6 min
Description: Video solution 1: [Solved] Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:(i) [Fe(CN)6]4− (ii) [FeF6]3− (iii) [Co(C2O4)3]3− (iv) [CoF6]3− - Chemistry Part-I

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Updated on: Nov 2, 2022

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Chemistry Part-I (NCERT)

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Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i)

[F e (CN)_{6}]^{4 -}

(ii)

[F e F_{6}]^{3 -}

(iii)

[C o (C_{2} O_{4})_{3}]^{3 -}

(iv)

[C o F_{6}]^{3 -}

7 mins ago

Discuss this question LIVE

7 mins ago

Text solutionVerified

(i)

[F e (CN)_{6}]^{4 -}

Co(III) with

3 d^{6}

outer electronic configuration is

d^{2} s p^{3}

hybridised. A diamagnetic octahedral complex is formed. It is inner orbital, low spin or spin paired complex.

(ii)

[F e F_{6}]^{3 -}

Fe(III) with

3 d^{5}

outer electronic configuration is

s p^{3} d^{2}

hybridised. A paramagnetic octahedral complex is formed. It is outer orbital, high spin or spin free complex.

(iii)

[C o (C_{2} O_{4})_{3}]^{3 -}

Co(III) with

3 d^{6}

outer electronic configuration is

d^{2} s p^{3}

hybridised. A diamagnetic octahedral complex is formed. It is inner orbital, low spin or spin paired complex.

(iv)

[C o F_{6}]^{3 -}

Co(III) with

3 d^{6}

outer electronic configuration is

s p^{3} d^{2}

hybridised. A paramagnetic octahedral complex is
formed. It is outer orbital, high spin or spin free complex.

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Practice more questions from Chemistry Part-I (NCERT)

What is the coordination entity formed when excess of aqueous

K CN

is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when

H_{2} S (g)

is passed through this solution?

Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i)

[F e (CN)_{6}]^{4 -}

(ii)

[F e F_{6}]^{3 -}

(iii)

[C o (C_{2} O_{4})_{3}]^{3 -}

(iv)

[C o F_{6}]^{3 -}

Draw figure to show the splitting of d orbitals in an octahedral crystal field.

View all

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Question Text	Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory: (i) $[F e (CN)_{6}]^{4 -}$ (ii) $[F e F_{6}]^{3 -}$ (iii) $[C o (C_{2} O_{4})_{3}]^{3 -}$ (iv) $[C o F_{6}]^{3 -}$
Updated On	Nov 2, 2022
Topic	Coordination Compounds
Subject	Chemistry
Class	Class 12
Answer Type	Text solution:1 Video solution: 1
Upvotes	159
Avg. Video Duration	6 min

Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i) $[F e (CN)_{6}]^{4 -}$ (ii) $[F e F_{6}]^{3 -}$ (iii) $[C o (C_{2} O_{4})_{3}]^{3 -}$ (iv) $[C o F_{6}]^{3 -}$

Text solutionVerified

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Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:(i) [Fe(CN)6​]4− (ii) [FeF6​]3− (iii) [Co(C2​O4​)3​]3− (iv) [CoF6​]3−

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Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i) $[F e (CN)_{6}]^{4 -}$ (ii) $[F e F_{6}]^{3 -}$ (iii) $[C o (C_{2} O_{4})_{3}]^{3 -}$ (iv) $[C o F_{6}]^{3 -}$